You can add a BCC to all outgoing emails with Postfix.
Code:
postconf -e "always_bcc = special_user@mydomain.tld"
http://www.postfix.org/postconf.5.html#always_bcc
Quote:
always_bcc (default: empty)
Optional address that receives a "blind carbon copy" of each message that is received by the Postfix mail system.
Note: if mail to the BCC address bounces it will be returned to the sender.
Note: automatic BCC recipients are produced only for new mail. To avoid mailer loops, automatic BCC recipients are not generated after Postfix forwards mail internally, or after Postfix generates mail itself.