The "Additional .ini files parsed" section in phpinfo() are for additional php config files, not for mysql files. PHP has no reason to read from the MySQL config file.
However, what you should see in phpinfo are MySQL and MySQLi sections. The presence of these will tell you that MySQL extension for PHP is installed and enabled. Check in your php.ini for the lines:
Code:
extension=php_mysql.so
extension=php_mysqli.so
If there is a semi-colon in front of those, then the extensions are disabled. Remove the semi-colons, and restart your web server and you should have success.